| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 가을 (10/07 ~ 10/08, 대구 EXCO) |
| 권호 |
35권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Synthesis and Self-Assembly of Diblock Copolymers Comprised of Semiconducting and Semifluorinated Segments by ATRP |
| 초록 |
This study reports the synthesis and self-assembly behavior of semiconducting-semifluorinated block copolymers comprised of regioregular poly(3-hexylthiophene) (P3HT) and poly(1H,1H-dihydro perfluorooctyl methacrylate) (PFOMA) segments by ATRP. The block copolymers were well characterized by 1H-NMR and GPC. TEM was used to investigate the nanostructured morphology of the diblock copolymers. The block copolymers are able to undergo microphase separation and self-assemble into well-defined and highly organized nanofibrillar-like micellar morphology. The development of the morphology of P3HT-b-PFOMA block copolymers was investigated after annealing in solvent vapor and also in supercritical CO2. |
| 저자 |
Harun1, 안1, 제갈영순2, 임권택1
|
| 소속 |
1부경대, 2경일대 |
| 키워드 |
semiconducting-semifluorinated block copolymers |
| E-Mail |
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