학회 | 한국화학공학회 |
학술대회 | 2006년 가을 (10/27 ~ 10/28, 고려대학교) |
권호 | 12권 2호, p.1911 |
발표분야 | 에너지/환경 |
제목 | Preparation of Pt/Nafion self-humidifying membranes for PEMFC (Polymer Electrolyte Membrane Fuel Cell) via supercritical-impregnation methods |
초록 | Pt/Nafion self-humidifying membranes for Polymer Electrolyte Membrane Fuel Cell (PEMFC ) were synthesized via supercritical-impregnation methods. The Nafion 112 membranes were impregnated with Pt(II)(acetylacetonate) from a supercritical carbon dioxide ( scCO2 ) solution at 80℃ and 30 MPa. After the impregnation, the pressure decreased slowly by releasing CO2. And the Pt-impregnated Nafion membrane was converted Pt deposited Nafion membrane by reducing agent, sodium borohydride ( NaBH ) with various concentrations under 50℃ and 2 hours. The prepared Pt-impregnated Nafion (Pt/Nafion) composite membrane were investigated by Electron Prove Micro analysis (EPMA) which showed distribution of Pt particle and Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM). which revealed morphology of surface of Pt/Nafion composite membrane. |
저자 | 신우균, 변정연, 김효원, 김화용 |
소속 | 서울대 |
키워드 | PEMFC; self-humidifying membrane; supercritical-impregnation; |
원문파일 | 초록 보기 |