화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터)
권호 40권 1호
발표분야 기능성 고분자
제목 Pyridinic N-rich nitrogen-doped graphene nanoplatelets for oxygen reduction reaction
초록 We report a facile wet-chemical method to produce high-quality pyridinic N–rich nitrogen-doped graphene nanoplatelets (PN-GNs). The efficient doping of nitrogen atoms into two-dimensional graphene networks can be obtained via acid–catalyzed dehydration reaction between GO and primary amine-containing small molecules. The nitrogen content in PN-GNs can easily be controlled over a wide range (3.27–15.28 wt.%) by simple variation in the molar feed ratio of reactants. Owing to specific pyridinic nitrogen configurations in PN-GNs, they show unique electrocatalytic activities (high selectivity, excellent long-term stability and good tolerance to methanol crossover) toward oxygen reduction reaction (ORR) in alkaline electrolyte.
저자 이민석, 장동욱
소속 부경대
키워드 nitrogen-doped; graphene; oxygen reduction reaction
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