화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 가을 (10/07 ~ 10/08, 대구 EXCO)
권호 35권 2호
발표분야 기능성 고분자
제목 High Tg Cyclic Olefin Copolymer Gate Dielectrics for N,N’-Ditridecyl Perylene Diimide-Based Field-Effect Transistors: Improving Performance and Stability with Thermal Treatment
초록 This poster reports a novel application of ethylene-norbornene cyclic olefin copolymers (COC) as gate dielectric layers in organic field-effect transistors (OFETs) that require thermal annealing as a strategy for improving the OFET performance and stability. The COC gate dielectric layer displays a hydrophobic surface (water contact angle = 95±1°) and high thermal stability (glass transition temperature = 181°C) without producing cross-linking. After thermal annealing, the n-type FETs with the COC gate dielectrics exhibit high atmospheric field-effect mobilities, up to 0.90 cm2V1s1 in the 20 V saturation regime and long-term stability with respect to H2O/O2 degradation, hysteresis, or sweep-stress over 120 days. By integrating the n-type FETs with p-type pentacene-based FETs in a single device, high performance organic complementary inverters that exhibit high gain (exceeding 45 in ambient air) are realized.
저자 장재영, 남수지, 박찬언
소속 포항공대
키워드 cyclic olefin copolymer; N; N’-ditridecyl perylene diimide; air stability; thermal annealing; organic field-effect transistors
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