| 학회 |
한국화학공학회 |
| 학술대회 |
2012년 가을 (10/24 ~ 10/26, 부산 BEXCO) |
| 권호 |
18권 2호, p.1759 |
| 발표분야 |
분리기술 |
| 제목 |
Separation of Iodine from HIx Mixture in SI Hydrogen Producing Process by Melt Crystallization |
| 초록 |
The Sulfur-Iodine thermochemical cycle (SI cycle) is one of the most promising processes to generate sufficient amount of hydrogen. The formerly announced section Ⅲ in SI cycle, which consists of concentration, decomposition and separation of HIx mixture, is the most important section because this section determines the hydrogen product yield of SI cycle. To decrease overall energy consumption, the iodine content in HIx mixture has to be reduced before this stream enters the cathode part of EED. Therefore, we recommend the crystallization process of the solid iodine as a separation method. In previous works, research on iodine separation from HIx mixture was performed by batch type crystallizer but in this study, we conducted iodine separation with continuous type crystallizer. Conducting follow-up experiment, samples were taken every 30 minute in upper and lower phase, and each composition was analyzed with auto titration. At temperature of 1 ℃ and 40 rpm speed of impeller, after 30 minute of residence time, separation of iodine in heavy phase was stably verified. |
| 저자 |
박선미1, 이범진1, 강경수2, 배기광2, 박병흥3, 강정원1
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| 소속 |
1고려대, 2한국에너지기술(연), 3한국교통대 |
| 키워드 |
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| E-Mail |
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| 원문파일 |
초록 보기 |
