화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2005년 봄 (04/14 ~ 04/15, 전경련회관)
권호 30권 1호, p.196
발표분야 복합재료
제목 Preparation and characterization of Clay-PLASB nanocomposites in situ polymerization.
초록 Composites of Poly(L-lactic acid-co-succinic acid-co-1,4-butanediol) (PLASB) were prepared by in situ polymerization with an organophilic clay having a special functional group, namely twice functionalized organoclay(TFC). The structure of the nanocomposites was analyzed by using X-ray diffractometry (XRD) (Fig 1.), thermo gravimetric analysis(TGA) and transmission electron microscopy(TEM)(Fig 2.). The silicate layers of PLLA/TFC were intercalated. Not only Young’s modulus but tensile strength was greatly enhanced as a result of the compounding.PLLA. The layer amount of exfoliation of the silicate layers in PLASB/TFC was attributed to the reaction between PLASB and TFC.



Fig 1. The structure of nanocomposites was X-ray diffractometry (XRD)
Fig 2. Transmission electron microscopy(TEM) of Clay-PLASB nanocomposites

참고문헌

1. G. X. Chen and J. S. Yoon, Polym Degrad Stabil, accepted.
저자 김훈식, 박병현, 윤진산
소속 인하대
키워드 nanocomposites; PLA; Clay
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