화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 고분자구조 및 물성
제목 Fabrication and Characterization of Polymer-Stabilized Coatable Polarizer
초록 Sunset Yellow FCF (H-SY) was self-assembled to oriented anisotropic films. The molecular packing structures and optical behaviors of the assembled H-SY film were investigated by the combined techniques of microscopy, scattering and spectroscopy. Photo-polymerization of acrylic acid (AA) was conducted to stabilize the oriented H-SY films and to minimize the possible defects after coating the H-SY/H2O solution. Utilizing the wide-angle X-ray diffraction, H-SY crystalline unit cell of the assembled H-SY film was determined to be monoclinic. The molecular arrangements were further confirmed by polarized Fourier transform infrared and polarized ultraviolet spectroscopy. The polymer-stabilized H-SY films showed good mechanical and chemical stabilities in addition to the high polarizerbility. Patterned polarizers were further fabricated by applying a photo-mask during photo-polymerization of AA, which may open new doors in optoelectronic devices.
저자 이상아1, 정광운1, 이종훈1, 송대현1, 이명훈1, 신승한2
소속 1전북대, 2한국생산기술(연)
키워드 lyotropic chromonic liquid crystal (LCLC); self-assembly; Sunset Yellow FCF; degree-of-polarization; polarized FT IR; order parameter
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