화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 고분자가공/복합재료
제목 Preparation of Transparent Conductive Films with High Transparency and Low Sheet Resistance by Dispersed Single-Walled Carbon Nanotubes Using Poly[2-(dimethylamino) ethyl methacrylate]-co-Polystyrene
초록 The SWNTs coatings on substrates have been investigated as TCFs to alternate indium tin oxide (ITO) films. One of important factors that makes TCF more conductive is the dispersion of SWNTs. However, SWNTs exist as a bundle due to a strong intertube van der Waals attraction. In order to obtain well dispersed SWNTs, efficient dispersants are firstly required. Here, poly(PDMAEMA-co-PS) was synthesized and used as a polymeric dispersant for SWNTs in organic solvent. PDMAEMA-co-PS with different copolymer compositions was prepared by ATRP. With PDMAEMA-co-PS, SWNTs were effectively dispersed through non-covalent functionalization by ultrasonication in THF. SWNTs coatings on PET and glass, were prepared via spin-coating method. Moreover, thermal treatment was carried out as a post-treatment to decrease the sheet resistance without the change of transparency. Transmittance and sheet resistance of SWNTs/ PDMAEMA-co-PS films were obtained by UV-vis and 4-point probe measurement, respectively.
저자 김현성1, 백현종1, 김봉수1, 신권우2
소속 1부산대, 2KETI
키워드 SWCNT; poly(DMAEMA-co-St); TCFs; post treatment
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