화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 기능성 고분자
제목 Light-Emitting Electrochemical Cells Based on Phosphorescent Iridium Complex Incorporated with Ionic Liquids
초록 A heteroleptic phosphorescent iridium complex [Ir(ppz)2(dmphen)]PF6, containing 1-phenylpyrazole (ppz) as cyclometalated ligand and 5,6-dimethyl-1,10-phenanthroline (dmphen) as ancillary ligand, has been synthesized and its photophysical and electrochemical properties have been investigated. Light-emitting electrochemical cells (LECs) based on this complex were fabricated using air stable electrodes resulting in a yellowish light emission. Furthermore, three different imidazolium based ionic liquids (ILs) such as 1-butyl-3-methylimidazolium hexafluorophosphate (BMIMPF6), 1-ethyl-3-methylimidazolium hexafluorophosphate (EMIMPF6) and 1-hexyl-3-methylimidazolium hexafluorophosphate (HMIMPF6) were incorporated into the active layer and hence the luminance and the current density of the devices were found to be enhanced with increasing ionic conductivities of ILs.
저자 수네쉬, 최영선, 옥순성, 문단비, 미둔
소속 부산대
키워드 Light-emitting electrochemical cells; Ionic liquids; irium complex
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