화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2004년 봄 (04/23 ~ 04/24, 공주대학교)
권호 10권 1호, p.664
발표분야 에너지/환경
제목 Study on performance of secondary lithium/sulfur battery with various weight ratios of S/FeS composite cathode
초록 The lithium/sulfur battery consists of composite cathode, polymer electrolyte, and lithium anode. The comp-osite cathode is made of elemental sulfur(or lithium sulfide), carbon black, P(VdF-co-HFP), LiClO4 and acetone. In the electrolyte of lithium/sulfur batteries, PE separator with mechanical strength is used in order to prevent the transfer discharging products such Li2S from cathode to the lithium anode. The cell using a dispersant had good cyclability and discharge/charge efficiency.
The cathode based on sulfur was prepared with different ratios of sulfur and iron(II) sulfide for the Li/S batteries. The cathode with the ratio of S:FeS = 8:2 showed the highest specific capacity and good battery performance at room temperature. To understand the effect of the iron on the electrochemical performance, the cells were characterized using FRA, CV, charging and discharging.
저자 김광현, 송주현, 연진희, 전병호, 정인재
소속 한국과학기술원
키워드 battery; sulfur
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