화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 분자전자 부문위원회
제목 Naphtho[1,2-b:5,6-b’]dithiophene-based conjugated polymer as a new electron donor for bulk-heterojunction organic solar cells
초록 We report for the first time the synthesis and photovoltaic application of a Naphtho[1,2-b:5,6-b’]dithiophene (NDT) which is symmetrical, planar, π-conjugated, and rigidly fused potential semiconductor containing donor-acceptor conjugated copolymer. The combination of thiophene-bridge NDT building block with a quinoxaline acceptor unit results in a new copolymer that has an optical band gap of 1.77 eV, a HOMO level of -5.24 eV, and a hole mobility of 5.0x10-5 cm2V-1s-1. Preliminary characterization of the bulk-heterojunction solar cell device exhibits a PCE of around 1.5%.
저자 Swapnil1, 오민재1, Pranabesh Dutta1, 박한옥1, 이우형2, 김규리1, 강인남2, 이수형1
소속 1전북대, 2가톨릭대
키워드 Donor-acceptor; Conjugated polymer; stille coupling
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