화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 봄 (04/10 ~ 04/11, 컨벤션 뷰로(대전))
권호 33권 1호
발표분야 고분자 합성
제목 In-siut grafting of carboxylic acid-terminated hyperbranched poly(ether-ketone) to the surface of graphite
초록 Graphite is considered as highly prospective filler materials for advanced polymer composites due to the high aspect ratio, superior electrical and thermal conductivity. However, because of the small in-plane spacing of the graphite layers and the lack of the affinity for polymers, it is rather difficult to prepare the conductive graphite/polymer nanocomposites via direct intercalation method. To achieve nanoscale dispersion of graphite in polymer matrix, certain chemical or physical modification to the graphite is generally needed. Less destructive chemical modification of various carbon nanotubes in a mild polyphosphoric acid (PPA)/phosphorous pentoxide (P2O5) medium has been developed. We prepared graphite nanocomposite with carboxylic acid-terminated hyperbranched poly(ether-ketone)s in PPA/P2O5 medium. The nanocomposites that were introduced three-dimensional globular dendritic macromolecules are expected to display enhanced solubility, available multi-functionality, and so on.
저자 전인엽1, Loon-Seng Tan2, 백종범1
소속 1충북대, 2US Air Force Research Lab
키워드 hyperbranched polymer; graphite
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