화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 고분자_포스터
제목 Synergetic Evolution of DPP-Based Polymeric Semiconductor for High Reproducibility and Performance
초록 A new random copolymer consisting of similarly shaped D-A building blocks of DPP-SVS and DPP-TVT is designed and synthesized. The resulting P-DPP-SVS(5)-TVT(5) with an equal molecular ratio of the two building blocks produced significantly enhanced solubility when compared to that of the two homopolymers, PDPP-SVS and PDPP-TVT. This unique property produces a high charge carrier mobility of 1.23 cm2V−1s−1 of PDPP-SVS(5)-TVT(5), as determined from organic thin film transistor (OTFT) measurements. The high solubility of PDPP-SVS(5)-TVT(5) promotes formulation of high-viscosity solutions which could be successfully processed to fabricate large-areal OTFTs onto hydrophobically treated 4 in. wafers. This result shows that producing devices with extremely narrow distribution of OTFT parameters. This is the first study to report on successfully realizing large-areal reproducibility of high-mobility polymeric semiconductors.
저자 김유헌1, 조장환2, 박성종1, 안은수1, 하재운2, 권순기1, 정대성3, 김윤희1
소속 1경상대, 2중앙대, 3대구경북과학기술원
키워드 OTFT; copolymer
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