| 학회 |
한국공업화학회 |
| 학술대회 |
2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션) |
| 권호 |
20권 1호 |
| 발표분야 |
환경에너지_포스터 |
| 제목 |
Electrochemically generated homogeneous Ni(I)(CN)43- towards gaseous CCl4 removal using electro-scrubbing |
| 초록 |
Gas pollutants must be removed to have healthy envirenmtal air for humans. Among amny ways to remove them, metal ions mediated electrochemical reduction (MER) is a futuristic technology. Metal complexes are more suitable to use as a mediator in the MER process due to stabilize the active low valent state of metal ion. The present investigation focuses on reduction of Ni(II)(CN)42- especially at the Cu electrode in KOH medium. At a first step, Pt electrode as anode in 5 M H2SO4 in anodic part kept constant. Electrolytic reduction of Ni(II)(CN)42- identified by ORP variation and potentiametric titration. Suitability of cathodes form Ag, Ti, carbon, and Cu in 10 M KOH solution were tested. The reduction efficiencies changes calculated using titration with KMnO4. Cyclic voltammetry analysis at said electrodes corelated with the reduction of Ni(II)(CN)42-. A model gas pollutant CCl4 removal carried out by electro-scrubbing with online FTIR gas analyzer. |
| 저자 |
A.G.Ramu, G.MUTHURAMAN, 문일식
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| 소속 |
순천대 |
| 키워드 |
Homogeneous mediator; Ni(II)(CN)42-; MER; degradation; CCl4.
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| E-Mail |
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