화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2016년 봄 (04/27 ~ 04/29, 부산 BEXCO)
권호 22권 1호, p.1025
발표분야 촉매 및 반응공학
제목 Investigation of Enhanced CO2 Reduction Activity in Association with the Electronic Surface State: Microscopic Physical Morphology and Chemical Structure Analyses
초록 There has been enormous recent interests in developing sustainable device, both reduce energy consumption and minimize pollution, due to increasing attention about environment issues. An efficient and stable electrochemical CO2 reduction catalyst has become a key technological target in chemical synthesis and processing. Nanostructure formation is a popular strategy for catalyst applications because it can generate new surfaces that can significantly improve catalytic activity and durability. However, the increase in the surface area via nanostructuring does not fully explain the substantial improvement in the catalytic properties. We show that the short Au-Au bond length and the low work function observed in the nanostructured Au surface are related to the catalytic activity of CO2 reduction. In addition, our results may improve the understanding of the enhanced stability of the nanostructured gold electrode based on the resistance of cation adhesion during the CO2 electro-reduction reaction.
저자 김해리1, 전효상2, Eduardus Budi Nursanto2, 지신천1, Jitendra Pal Singh1, 채근화1, 황윤정2, 민병권2
소속 1KIST, 2KIST / UST
키워드 산화환원촉매; 촉매반응메커니즘
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