화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 봄 (05/12 ~ 05/14, 부산 벡스코(BEXCO))
권호 25권 1호
발표분야 학생우수논문발표(박사과정)
제목 Visible-light sensitive TiO2 catalysts for photocatalytic activity: Effect of calcination temperature
초록 TiO2 is one of the most widely used photocatalysts owing to its light-harvesting ability and non-toxicity. However, applications of TiO2 have restricted under UV region. To improve the light adsorption, mesoporous TiO2 catalysts were synthesized by soft-template assisted hydrothermal method. The prepared TiO2 catalysts were calcined at different temperatures in the range of 100-1300 ℃ to investigate how their crystalline phases, specific surface area, and band gap energies affect their photocatalytic performance. TiO2 existed in the anatase phase until 700 ℃ and anatase-to-rutile phase transformation occurred at above 700 ℃. The band gap energies gradually decreased with the increase in the calcination temperature. We demonstrate that TiO2 calcined at 1100 ℃ was the highest degradation of methyl violet 2B under visible light irradiation despite of its lower surface area and porosity.
저자 김예은1, 변미연1, 이관영2, 이만식1
소속 1한국생산기술(연), 2고려대
키워드 Calcination; Photocatalysis; Photodegradation; TiO2
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