| 초록 |
Static self-assembly is the spontaneous organization of molecular components through noncovalent interactions which has focused exclusively on thermodynamic equilibrium conditions. It is, however, important to understand dynamic self-assembly far-from equilibrium systems, which holds promise to give interesting supramolecular systems as typified by the life of the cell. In this talk, we will demonstrate the significance of collaborative interplay between static and dynamic self-assemblies. First, molecular flux across the liquid-liquid interface provides unique supramolecular nanoparticles of peptides and proteins, where guest biopolymers are quantitatively encapsulated. Second, vectorial flux of ions from ionic liquids to aqueous phase directs the emergence of dissipative morphologies of cyanine J-aggregates such as U-shaped fibers and dendrites. The unique feature and possible applications of these self-assemblies will also be discussed. |
