| 학회 | 한국고분자학회 |
| 학술대회 | 2005년 가을 (10/13 ~ 10/14, 제주 ICC) |
| 권호 | 30권 2호 |
| 발표분야 | 기능성 고분자 |
| 제목 | Poly(arylene ether)s Containing Carboxylic and Sulfonic Acid Groups for Proton Exchange Membrane Materials |
| 초록 | Proton conducting polymers have attracted much attention due to their applications in some electrochemical devices, such as proton exchange membranes (PEM) in PEM fuel cells (PEMFC) and direct methanol fuel cells (DMFC). Recently, sulfonated aromatic polymers such as sulfonated poly(ether ether ketone), poly(ether sulfone), polyimides, and poly(benzimidazole) have been investigated as candidate PEM materials because of their excellent thermal, mechanical, and dielectric properties and good oxidative resistance. In this study, Poly(arylene ether)s containing carboxylic and sulfonic acid groups were synthesized via nucleophilic aromatic substitution (SNAr) reaction of the monomers, 4-[bis-(4-nitro-3-trifluoromethyl-phenyl) amino] benzenesulfonic acid, 3,5-dihydroxy-benzoic acid and 4,4’-isopropylidenediphenol. Structure analysis by means of 1H NMR and FT-IR spectra showed the presence of two functional groups. |
| 저자 | 최형삼, 이몽섭, 김상율 |
| 소속 | 한국과학기술원 화학과 |
| 키워드 | Proton Exchange Membrane Materials; Poly(arylene ether)s |
