| 학회 | 한국고분자학회 |
| 학술대회 | 2005년 가을 (10/13 ~ 10/14, 제주 ICC) |
| 권호 | 30권 2호 |
| 발표분야 | 분자전자 부문위원회 |
| 제목 | Synthesis and photophysical properties of polybenzothiadiazole for fluorescent anion sensing |
| 초록 | Recently, fluorene-based π-conjugated polymers have emerged as a very promising candidate for polymer light-emitting diodes (PLEDs) due to their combined desirable properties, such as high fluorescence quantum yield and hole-transporting properties. We designed and synthesized the polybenzothiadiazole through Suzuki cross-coupling between 4,7-dibromo-2,1,3-benzothiadiazole and 9,9-dihexylfluorene-2,7-(bistrimethyleneborate). The obtained polymer was characterized with NMR, IR, GPC, UV/vis and fluorescence spectroscopy. The polymer, emitting intense green fluorescence, has higher binding capacity for fluoride anion (F-) than thoese of other anions. Fluorescence of emission change of polybenzothiadiazole upon addition of F-, Cl-, SO42- in THF (excitation at 452nm) |
| 저자 | 김형준, 이정효, 이택승 |
| 소속 | 충남대 |
| 키워드 | benzothiadiazole; fluoride; anion sensing |
