화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 봄 (05/12 ~ 05/14, 부산 벡스코(BEXCO))
권호 25권 1호
발표분야 포스터-환경·에너지
제목 Sunlight-induced photoelectrocatalytic wastewater treatment and hydrogen production coupled with desalination by reduced titania nanorods and Ni-Mo-S catalysts
초록  The desalination of brackish water in the desalination cell is initiated via photoinduced charge generation with a thermochemically reduced TiO2 nanorod array photoanode. The chlorides transferred to the neighboring anolyte at ion-transport efficiency of ∼100% are photoelectrochemically transformed into reactive chlorine species responsible for the decomposition of urea into nitrate in the anolyte. Simultaneously, the H2 production with a Ni–Mo–S (Ni2S3/MoS2) composite catalyst grown onto porous Ni substrate is achieved at Faradaic efficiency of ∼90% in the catholyte concentrated with desalted Na+.

This study has been conducted with the support of the National Research Foundation of Korea (2019R1A2C2002602), and the Ulsan Metropolitan City as “Development of Carbon Dioxide Capture and Utilization Technology for Greenhouse Gas Reduction”(U201900107).
저자 김성훈1, 임동하1, 박현웅2
소속 1한국생산기술(연), 2경북대
키워드 Photoelectrocatalytic desalination; Hydrogen production; wastewater desalination; reduced TiO2; Ni3S2/MoS2
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