화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 KRICT 미래 소재 및 공정
제목 Ensemble and ligand effect on PdAu catalyzed formic acid dehydrogenation
초록 The combination of two metals often promotes the catalytic performance compared to their single usages. Gold has known to enhance the catalytic activity and selectivity of palladium catalyzed formic acid dehydrogenation. In this talk, we present the effect of gold addition on the palladium catalyzed formic acid dehydrogenation by experimental and computational studies. The perturbation of d-band structure (ligand effect) and the variation of surface palladium arrangement (ensemble effect) were evidenced to affect catalytic activity.
저자 이진희1, 조진원2, 함형철2, 윤창원2
소속 1한국화학(연), 2한국과학기술(연)
키워드 Formic acid dehydrogenation; Palladium-gold; Ensemble effect; Ligand effect
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