학회 |
한국화학공학회 |
학술대회 |
2003년 가을 (10/24 ~ 10/25, 한양대학교) |
권호 |
9권 2호, p.2830 |
발표분야 |
촉매/반응공학 |
제목 |
Development of Gasoline Fuel Reformer for Fuel Cell Powered Vehicles : Ceria-based Water Gas Shift Catalysts |
초록 |
On-board fuel processor is the most convenient method of supplying hydrogen in the absence of a suitable infrastructure for hydrogen. The WGS reaction is one of the key catalytic stages in a fuel processor. Existing commercial Cu-Zn/Al2O3 (LTS) catalyst, though highly active, was unsuitable for fuel cell powered transportation applications. The WGS reaction over Pt- and (or) Ni-containing cerium oxide catalysts was investigated to develop a high performance WGS catalyst with high stability. The thermal cycling performance over the prepared catalysts was compared with that over the commercial Cu-Zn/Al2O3 catalyst. It was found that Pt-Ni/ceria catalysts displayed reasonably good activity than Cu-Zn/Al2O3 catalyst. It was also found that Ni-Pt/ceria catalysts showed higher stability than the commercial LTS catalyst during thermal cycling test. These results suggest that the Pt-Ni/Ceria catalysts are attractive candidates for development as the alternate commercial LTS catalyst for the fuel cell powered vehicles applications. |
저자 |
류종우1, 문동주1, 이상득1, 이병권1, 홍석인2
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소속 |
1한국과학기술(연), 2고려대 |
키워드 |
Gasoline; Fuel Processor; WGS; Ceria; Catalyst
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E-Mail |
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VOD |
VOD 보기 |
원문파일 |
초록 보기 |