| 학회 |
한국공업화학회 |
| 학술대회 |
2014년 봄 (04/30 ~ 05/02, 제주국제컨벤션센터) |
| 권호 |
18권 1호 |
| 발표분야 |
포스터-정보.전자소재 |
| 제목 |
An Ionic Conjugated Polymer from the Non-catalyst Polymerization of 2-Ethynylpyridine via the Ring-Opening of Cyclic Compounds: Synthesis and Characterization |
| 초록 |
A self-dopable conducting polymer was defined as a conjugated polymer where a significant fraction of monomeric unit contained a covalently attached ionizable. Here, a novel ionic conjugated polymer was synthesized via the non-catalyst polymerization of 2-ethynylpyridine by the ring-opening of cyclic compound. The polymerization of 2-ethynylpyridine by using cyclic compounds proceed well in homogeneous manner even at the mild reaction conditions to give a high yield of polymer. The cyclovoltammograms of polymer exhibited the irreversible electrochemical behaviors between the oxidation and reduction peaks. The oxidation current density of polymer versus the scan rates is approximately linear relationship in the range of 30 mV/sec – 120 mV/sec. |
| 저자 |
제갈영순1, 진성호2, 박종욱3, 심상연4, 임권택5
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| 소속 |
1경일대, 2부산대, 3가톨릭대, 4강릉원주대, 5부경대 |
| 키워드 |
polyacetylene; 2-ethynylpyridine; non-catalyst polymerization; photoluminescence; cyclic voltammogram
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| E-Mail |
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