화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 가을 (10/08 ~ 10/09, 광주과학기술원 오룡관)
권호 34권 2호
발표분야 고분자 구조 및 물성
제목 Stimuli-Driven Release of Model Polymersfrom Polyelectrolyte Multilayer Films Monitored by Neutron Reflectivity
초록 In this study, we have studied on the release mechanism of deuterated target polymer chains incorporated into multilayered films using neutron reflectivity (NR). NR experiments allow us to gain the quantitative information on the change of internal structure upon external perturbations and also on the release of a specific component in the mixed layers when one component in the mixture is deuterated and subject to release upon exposure to external stimuli. Using NR, we successfully monitored the release behavior of d-PMAA in nanocomposite multilayer films containing a mixture of anionic weak (PMAA) and strong (PSS) polyelectrolytes. We also have investigated the effect of post-treatment pH on the release of d-PMAA from the multilayer films in detail.
저자 장영선1, 차국헌1, Bulent Akgun2, Susil Satija2
소속 1서울대, 2NIST Center for Neutron Research
키워드 Stimuli-Driven Release; Polyelectrolyte Multilayer Films; Neutron Reflectivity
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