화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 고분자 구조 및 물성
제목 Fabrication and Photocatalytic Activities of Hybrid Metal/Semiconductor Nanostructures using Self-Assembled Block Copolymer Thin films as Templates
초록 The wide-band-gap semiconductor metal oxides, such as TiO2 and ZnO, have been remarkably noticed due to high catalytic efficiency, low cost and sustainability for environment. In addition, they can also be practically applied as elements in photovoltaic, light emitting devices, solar cells, etc. Herein, we investigated the influence of Au or Ag metal nanoparticles on photocatalytic activities of hybrid metal/semiconductor nanostructures. Using PS-b-PEO and PS-b-P4VP diblock copolymer as templates, hexagonally ordered hybrid metal/semiconductor nanodot arrays such as Au or Ag combined with TiO2 or ZnO were fabricated. Enhanced catalytic efficiency by surface plasmon of Au or Ag could be observed in photodegradation of dyes. Inner morphologies and optical properties are also demonstrated by atomic force microscopy, transmission electron microscopy, UV-vis spectroscopy, and fluorescence spectroscopy.
저자 장윤희, 차민아, 김동하
소속 이화여자대
키워드 metal/semiconductor; TiO2; ZnO; photocatalytic activity; block copolymer
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