| 학회 |
한국공업화학회 |
| 학술대회 |
2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 |
8권 2호 |
| 발표분야 |
정밀화학 |
| 제목 |
Polymer-Supported Palladium-Carbene Complex for Suzuki Cross-Coupling Reaction in Aqueous Phase |
| 초록 |
Poly(1-methylimidazoliummethyl-tetraethyleneglycol-styrene)-co-polystyrene(PS-co-PS-TEG-MI) resin (38~200㎛) was prepared by suspension polymerization. The resin was compatible with water, and all the imidazolium functional groups were located on the bead surface. To obtain this resin, 1-methyl-4-vinylbenzyltetraethylene glycol imidazolium hexafluorophosphate was synthesized and copolymerized with styrene and DVB under suspension polymerization condition. This new type resin was used as a polymer-supported carbene precursor for palladium complex. The polymer- supported palladium reagent efficiently catalyzed Suzuki cross-coupling of various aryl halides and aryl boronic acids in aqueous phase. |
| 저자 |
김정우, 김종호, 이윤식
|
| 소속 |
서울대 |
| 키워드 |
Polymer-Support; Palladium; Suzuki
|
| E-Mail |
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