| 학회 |
한국고분자학회 |
| 학술대회 |
2002년 봄 (04/12 ~ 04/13, 서울대학교) |
| 권호 |
27권 1호, p.254 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Vinyl-type Polymerization of Polynorbornene Dicarboxylic Acid Dialkylester |
| 초록 |
Norbornene can be polymerized by ring-opening metathesis, cationic, and vinyl-type polymerization, and the vinyl-type polymer has good thermal stability, high transparency and low dielectric constant. However, it has low solubility, and poor mechanical and adhesive properties. In this work, norbornene dicarboxylic acid dimethylester and norbornene dicarboxylic acid diethylester were polymerized as a vinyl-type by Pd catalyst without cocatalyst. The polymer shows good solubility in general organic solvents and good thermal stability to 350 ℃. No glass transition temperature was detected by DMA, DSC experiment prior to the onset of decomposition at 350 ℃. In conclusion, polymer solubility and adhesive property were improved by introducing polar group, while preserving the good thermal stability. |
| 저자 |
신부교1, 윤도영2, 장명석*3, Walter Heitz*4
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| 소속 |
1서울대, 2*Philipps-Univ. of Marburg, 3Department of Chemistry, 4Hans-Meerweinstr. |
| 키워드 |
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| E-Mail |
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