| 학회 |
한국공업화학회 |
| 학술대회 |
2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스)) |
| 권호 |
8권 2호 |
| 발표분야 |
촉매 |
| 제목 |
Synthesis of polycarbonates by copolymerization of carbon dioxide and glycidyl methacylate using ionic liguids |
| 초록 |
The copolymerization of glycidyl methacrylate (GMA) and carbon dioxide was performed without any solvent in the presence of ionic liquid as catalyst. The reaction was conducted in a batch autoclave reactor. The conversion of glycidyl methacrylate was affected by the structure of imidazolium salt ionic liquid; the one with the cation of bulkier alkyl chain length and with more nucleophilic anion showed better reactivity. However, the yield of carbon dioxide addition decreased when a hexyl and octyl group containg ionic liquids are used in place of butyl group in 1-alkyl-3-methyl imidazolium salts. The conversion of glycidyl methacrylate increased as reaction temperature and CO2 pressure increased. The ionic liquids showed high activity to yield polycarbonates of narrow polydispersity and moderate molecular weight at mild reaction conditions. |
| 저자 |
문나영, 박대원, 김경훈, 주혜영, 김 일
|
| 소속 |
부산대 |
| 키워드 |
GMA Copolymerization; CO2; Ionic Liquid
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| E-Mail |
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