화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2000년 봄 (04/21 ~ 04/22, 한양대학교)
권호 6권 1호, p.953
발표분야 열역학
제목 열역학적 섭동 이론에 근거한 Hard-sphere 사슬 유체에 관한 새로운 상태방정식
초록 New equations of state for the freely jointed hard sphere chain fluids are developed. The equations of state are based on Wertheim’s thermodynamic perturbation theory. In developing the new equations of state we use the contact values of the radial distribution functions (RDF) of equimolar mixtures of monomer and dimer fluids as an intermediate reference system. For this purpose two expressions for the contact values of the RDF are adopted from the multidensity Ornstein-Zernike integral equation theory and the Monte Carlo simulation results.
저자 김연욱, 염민선, 장재언, 김화용
소속 서울대
키워드 TPT; perturbation theory; hard sphere chain fluid; SAFT; integral equation; equation of state
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