화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2017년 봄 (04/26 ~ 04/28, ICC 제주)
권호 23권 1호, p.750
발표분야 에너지 환경
제목 Binder and carbon-free ZnCo2O4 electrode for high-performance supercapacitor and methanol electro-oxidation application  
초록 The transition metal oxides play key role in realizing cost-effective energy storage systems by exhibiting outstanding electrochemical activity and stability. Free standing 3D ZnCo2O4 microspheres grown on nickel foam (NF) substrate by hydrothermal route. 3D ZnCo2O4 microspheres with high surface area and uniform mesoporous distribution exhibits high electrochemical performance. The ZnCo2O4/NF electrode materials deliver superior specific capacitance of 1143 F g-1 at a current density of 1.25 A g-1 in aqueous 2M KOH solution and exhibits long-term cycling stability with specific capacitance of 880 F g-1 after 6000 cycles at 12.5 A g-1. Furthermore, ZnCo2O4/NF electrode maintains current density upto 105 A g-1 in 1M KOH mixed with 0.5 M methanol when applied as electro-catalyst for methanol electro-oxidation. The present synthesis approach can open new era for large-scale applications of the novel materials for different electrochemical applications. This work was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (NRF 2016R1D1A1B03930855).
저자 Harsharaj Sayaji Jadhav, Roy Animesh, 서정길
소속 명지대
키워드 에너지전환
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