화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2013년 봄 (04/24 ~ 04/26, 광주 김대중컨벤션센터)
권호 19권 1호, p.743
발표분야 재료
제목 Determination of Coprecipitation pH for Preparing the Nickel-Manganese-Cobalt Mixed hydroxides
초록 Lithium nickel-manganese-cobalt oxides (LiNixMnyCo1-x-yO2) have been extensively studied as a promising cathode material for high-energy density lithium-ion battery systems. Lithium nickel-manganese-cobalt oxides synthesized by solid-state method often result in an inhomogeneous elemental distribution or the presence of impurity phase, leading to inferior electrochemical cycling performance. To obtain an ideal cathode material with high-capacity and high-performance, the use of a homogeneous precursor of mixed-hydroxides ((NixMnyCo1-x-y)(OH)2) is widely adopted. Coprecipitation processes often use ammonia water producing a plenty of nitrogen compounds that are characteristic of pungent smell and environmentally unfriendly. In this presentation, we report a novel non-ammonia coprecipitation method using a chelating agent and the method for calculration and determination of optimum pH condition for the preparation of homogeneous mixed-hydroxides.
저자 김현진1, 남경모1, 송승완1, 강동현2, 김용석2
소속 1충남대, 2Energy Material Tech
키워드 lithium-ion battery; electrochemical
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