화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 봄 (04/11 ~ 04/12, 대전컨벤션센터)
권호 38권 1호
발표분야 기능성 고분자
제목 Nonvolatile switching devices fabricated with Donor-Acceptor Polymer System
초록 The polymer with donor-acceptor system can play a role of charge trap sites in memory devices. We synthesized new polymers of poly(9-(4-vinylphenyl)carbazole)-b-poly(2-vinylpyridine) (PVPCz-b-P2VP) and poly(2-(N-carbazolyl)ethyl methacrylate) end-capped with fullerene (PCzMA-C60) consisting of electron donors as carbazole (PVPCz, PCzMA) and electron acceptors as pyridine and fullerene (P2VP, C60)by anionic polymerization. In case of poly(9-(4-vinylphenyl)carbazole)-b-poly(2-vinylpyridine) (PVPCz-b-P2VP), The devices based on donor-acceptor ratios system showing a lamellar structure of PVPCz59 block copolymer exhibited non-volatile memory performance. Especially, the polymer on high loaded C60(PCzMA-C60) has bipolar and unipolar non-volatile memory behaviors with excellent reliability, stable endurance, and long retention time.
저자 김명진1, 이재석1, 강남구2, 강범구3, 유용군1, 조병진1, 송성훈1, 함석규1, 권원상1, 김경태4, 고영기4, 이문호4, 이탁희4
소속 1광주과학기술원, 2신소재 공학부, 3나노바이오재료전자공학과(WCU), 4포항공과대
키워드 donor-acceptor polymer; nonvolatile memory
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