| 학회 |
한국공업화학회 |
| 학술대회 |
2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스)) |
| 권호 |
10권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Novel Hydroxy-terminated Copolyether-based Polyurethane system |
| 초록 |
Two novel synthetic routes were proposed for random hydroxy-terminated poly(EO-ran-THF) and tri-block PEG-PTHF-PEG copolymer by cationic ring-opening polymerization of tetrahydrofuran(THF) and ethylene oxide(EO) in the presence of 1,4-butandiol or just by polymerization of EO on poly(THF), respectively. Polyurethane was synthesized from random and tri-block HTPE using N-100/IPDI mixture as curing agent with TPB(Triphenylbismuth)/DNSA(dinitrosalicylic acid) as cure catalyst. The mechanical properties of resultant polyurethane after curing with various ratio of isocyanate was also investigated. Reactivity of hydroxyl-group was also investigated using titration method of NCO content during polyurethane reaction. |
| 저자 |
유호준1, 이범재1, 송종권1, 판샤오1, 강철한1, 이정환1, 김나리1, 박영철2
|
| 소속 |
1충남대, 2국방과학(연) |
| 키워드 |
hydroxy-terminated polyether; cationic ring-opening polymerization; polyurethane
|
| E-Mail |
|
