| 학회 |
한국공업화학회 |
| 학술대회 |
2010년 가을 (10/27 ~ 10/29, 대전컨벤션센터) |
| 권호 |
14권 2호 |
| 발표분야 |
미래 석유화학 연구동향 |
| 제목 |
메조포어 실리카에 고정화된 Rh 촉매를 이용한 옥텐 Hydroformylation |
| 초록 |
The selective functionalized MCM-41-based heterogeneous catalysts were applied toward the 1-octene hydroformylation. MCM-41 materials with amine and Rh complexes in the intra-pores show a higher selectivity for linear aldehydes. The mesopore, the steric bulky triphenylphosphine ligand greatly improved the selectivity of the less hindered linear aldehydes over the branched aldehyde. The active species involved in the hydroformylation has been studied by in situ FT-IR. The active species containing Rh(CO)2(PPh3)2 and HRh(CO)(Ph3P)3 were involved in the hydroformylation of 1-octene over the heterogeneous catalyst systems. |
| 저자 |
전종기, 송기창, 윤소영, 고영수, 임진형
|
| 소속 |
공주대 |
| 키워드 |
메조포어 실리카; 로듐; Hydroformylation
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| E-Mail |
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