| 학회 |
한국고분자학회 |
| 학술대회 |
2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO)) |
| 권호 |
44권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Multifunctional Polysulfide Polymers via Inverse Vulcanization of Sulfur and Allyl Glycidyl Ether: Shape-Memory Effect and Energy Storage Applications |
| 초록 |
Recent discovery of inverse vulcanization have set up a facile protocol to synthesize versatile high sulfur content polymers. Despite the variety of available comonomers, the chemistry of inverse vulcanization is limited to the addition of thiyl radicals, generated from sulfur, to unsaturated C-C bonds of comonomers. Such lack in the available chemistry poses a major obstacle in modulating physicochemical properties of resultant polymers. To develop new classes of monomers with new modes of reaction in the process, we herein report the use of epoxide-bearing allyl glycidyl ether (AGE) as comonomer which results in the formation of stable, low Tg polymers. Furthermore, electrochemical performance and dynamic mechanical behavior, especially shape memory effect of the polymer was systematically studied to demonstrate its versatile functionalities. |
| 저자 |
박상우1, 정민주1, Alexandros Lamprou2, 임지우3, 손정곤4, 차국헌1
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| 소속 |
1서울대, 2BASF, 3경희대, 4한국과학기술(연) |
| 키워드 |
Inverse vulcanization; Sulfur coplymer; Shape memory; Battery
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| E-Mail |
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