| 학회 |
한국공업화학회 |
| 학술대회 |
2007년 가을 (11/02 ~ 11/03, 한경대학교) |
| 권호 |
11권 2호 |
| 발표분야 |
고분자 |
| 제목 |
Synthesis of MPEG-b-Poly(BMA-co-TMSMA) using PEO-macro initiaor via Atom Transfer Radical Polymerization |
| 초록 |
The well-defined block copolymer derived from benzyl methacrylate(BMA) and trimethylsilyl methacrylate(TMSMA) was synthesized by the atom transfer radical polymerization(ATRP) with MPEG as a macro-initiator and CuBr/bpy as a catalyst system. The one of living radical polymerization was proceeded to control the molecular weight, narrow molecular weight distribution, and the functionality. The structure and the composition of synthesized copolymers have been characterized by 1H-NMR spectroscopy. The molecular weight and the molecular weight distribution of their copolymer have been analyzed by gel-permeation chromatography (GPC). |
| 저자 |
정권영, 이범재, 이정환, 유호준, 김나리, 김두환, 이종섭, 신범식, 김태중
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| 소속 |
충남대 |
| 키워드 |
MPEG-block-Poly(BMA-co-TMSMA); Atom Transfer Radical Polymerization(ATRP)
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| E-Mail |
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