초록 |
Energetic binders play the essential role in the development of high performance and IM technology. Novel synthetic methodology for the various molecular explosive-embedded polyetherdiol was provided by the wide spectrum of azide-alkyne "click" reaction. Ing this study, we synthesized 2,2-dinitroproply propiolate ester(DNPPE) and poly(GAP-co-THF). 1,2,3-Triazole-embedded copolyether polyol could be synthesized by Cu(I)-catalyzed 1,3-dipolra cycloaddition between the poly(GAP-co-THF) and DNPPE. The 1,2,3-trizole with high formation and triazole based salts are promising as energetic materials. |