화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2015년 봄 (04/08 ~ 04/10, 대전컨벤션센터)
권호 40권 1호
발표분야 대학원생 구두발표 (영어발표, 발표15분)
제목 Efficient Perovskite Solar Cells based on New Hole Transporting Conjugated Polymer and a Novel Method for Hole Mobility Measurement: TMS
초록 Recent developments in light absorber materials based on perovskite have yielded PCE exceeding 15% in hybrid solar cells. In this work, hybrid solar cells based on a CH3NH3PbI3 perovskite and a diketopyrrolopyrrole based hole transport polymer was successfully prepared. The excellent optical and electrical properties of perovskite used as a light harvester yielded a 9.2% PCE for the best-performing cell. The high PCE was attributed to the optimal oxidation potential (5.4 eV) and excellent charge carrier mobility of the polymer. The long-term stability of the PDPPDBTE devices, as measured over 1000 hours under a humid atmosphere, guarantees the practical applicability of these solid-state hybrid solar cells under outdoor working condition due to its hydrophobic condition. These results suggest a broad strategy for developing efficient organic semiconductors, and further enhancements may potentially be realized by carefully tuning the energetic distributions of the HTP and perovskite.
저자 강경호1, 박태호1, 권영수2, 임종철1, 김윤희3
소속 1포항공과대, 2삼성디스플레이, 3경상대
키워드 perovskite; D-A type polymer; hole mobility
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