화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션)
권호 20권 1호
발표분야 고분자_포스터
제목 Synthesis of highly crosslinked dicyclopentadiene polymer films using PECVD and their applications.
초록 We successfully synthesized plasma-polymerized films from a highly crosslinkable monomer, dicyclopentadiene using a low-temperature plasma process as an anti-corrosion coating for Cu metal plates. Plasma-enhanced deposition of polymer films from a dicyclopentadiene precursor was carried out using radio frequency (13.6 MHz) plasma generation with argon or nitrogen carrier gas and varying the input power. The surface of plasma-polymerized PDCPD using argon carrier gas was more hydrophobic than with nitrogen carrier gas, which can be attributed to the formation of C-N-CHx bonds from nitrogen dissociation. All plasma-polymerized films showed very high inhibition efficiencies, although the plasma-polymerized DCPDs had different anti-corrosion properties depending on the carrier gas. And also, we confirmed the anti-corrosion properties of plasma-polymerized PDCPD films using cell viability experiment, which is in well accord with the anti-corrosion measurement by electrochemistry.
저자 정동철, Amjed Javid, 문룡, 최은정, 박수연, 김용호, 한전건, 송창식
소속 성균관대
키워드 Plasma polymerization; Anti-corrosion; Norbornene;
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