학회 |
한국고분자학회 |
학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
권호 |
35권 1호 |
발표분야 |
고분자 구조 및 물성 |
제목 |
Synthesis and Characterization ofSulfonated Poly(ether sulfone)sfor Proton Exchange Membrane Fuel cell |
초록 |
poly(ether sulfone)s with bisphenol-TP and bisphenol-A <PBTP-BPA>, or bisphenol -AF <PBTP-BAF> were prepared with Bisphenol-TP <4,4-dihydroxy tetraphenyl methane>, 4-Fluorophenyl sulfone and bisphenol-A or bisphenol-AF <4,4-(hexafluoroisopropylidene)diphenol> using potassium carbonate in sulfolane <tetramethylene sulfone> at 210 ℃. Sulfonated PBTP-BPA and PBTP-BAF were obtained by reaction of chlorosulfuric acid with copolymers. A series of copolymers were studied by 1H-NMR spectroscopy, differential scanning calorimeter (DSC), and thermo gravimetric analysis (TGA). Sorption experiments were conducted to observe the interaction of sulfonated polymers with water and methanol. |
저자 |
임영돈, 서동완, 이순호, 진현미, 모니룰, 장호현, 김환기
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소속 |
건국대 |
키워드 |
PEMFC; bisphenol TP; biphenol AF; poly(ether sulfone)s; sulfonation
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E-Mail |
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