화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터)
권호 35권 1호
발표분야 고분자 구조 및 물성
제목 Synthesis and Characterization ofSulfonated Poly(ether sulfone)sfor Proton Exchange Membrane Fuel cell
초록 poly(ether sulfone)s with bisphenol-TP and bisphenol-A <PBTP-BPA>, or bisphenol -AF <PBTP-BAF> were prepared with Bisphenol-TP <4,4-dihydroxy tetraphenyl methane>, 4-Fluorophenyl sulfone and bisphenol-A or bisphenol-AF <4,4-(hexafluoroisopropylidene)diphenol> using potassium carbonate in sulfolane <tetramethylene sulfone> at 210 ℃. Sulfonated PBTP-BPA and PBTP-BAF were obtained by reaction of chlorosulfuric acid with copolymers. A series of copolymers were studied by 1H-NMR spectroscopy, differential scanning calorimeter (DSC), and thermo gravimetric analysis (TGA). Sorption experiments were conducted to observe the interaction of sulfonated polymers with water and methanol.
저자 임영돈, 서동완, 이순호, 진현미, 모니룰, 장호현, 김환기
소속 건국대
키워드 PEMFC; bisphenol TP; biphenol AF; poly(ether sulfone)s; sulfonation
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