학회 |
한국공업화학회 |
학술대회 |
2009년 봄 (04/15 ~ 04/17, 호텔인터불고(대구)) |
권호 |
13권 1호 |
발표분야 |
전기화학 |
제목 |
Study on characteristics of phosphoric acid doped on silica fuel cell |
초록 |
Electric characteristics of phosphoric acid fuel cell composed of silica substrate and Pt adsorbed on carbon nanotube electrode was observed at 100 ~ 200 ℃. Silica substrate was prepared by pressing of rice husk silica (RHS) with nano pore and sintering at 1200 ℃ and used as electrolyte and electrode support for fuel cell. Carbon nanotubes were synthesized by thermal decomposition of C2H2 on iron oxide catalyst at 700 ℃. Pt cluster adsorbed on carbon nanotubes were prepared by Pt reduction reaction of H2PtCl6. As operating temperature increased, the performance of CNT/Pt|H3PO4/RHS|Pt/CNT unit cell increased and OCV and maximun power density at 200 ℃ were 0.76 V and 0.88 mW/cm2. Apparent activation energy of CNT/Pt|H3PO4/RHS|Pt/CNT unit cell in the range 100 ~ 200 ℃ was 7.5 kJ/mol. |
저자 |
황문진, 류광선
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소속 |
울산대 |
키워드 |
Phosphoric acid fuel cell; Rice husk silica
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E-Mail |
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