화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 고분자합성
제목 Polyacrylonitrile (PAN) Terpolymers Containing Neutral and Acidic Comonomers for Carbon Fiber Precursor using Stepwise Solution Polymerization
초록 Carbon fiber is manufactured by heating and carbonizing organic fiber under inert gas and it has excellent specific strength, elastic modulus, thermal and chemical resistance. Due to those advantages, carbon fiber has been extensively applied in high-tech fields such as aerospace, defense areas, and civil engineering as reinforcing material. However, PAN homopolymer as the carbon fiber precursor has hardly been used because of its high stabilization temperature, centralized heat release and poor solubility. Moreover, the mechanical and thermal properties of PAN carbon fibers are highly affected by chemical structure and content of comonomer in PAN copolymer. In this study, PAN co- or terpolymers as carbon fiber precursor were successfully synthesized using methyl acrylate (MA), fumaric acid (FA) or maleic acid (MA) as comonomers via stepwise solution polymerization according to the different composition and weight ratio.
저자 노지영1, 임정혁2, 김경민2
소속 1국립한국교통대, 2한국교통대
키워드 PAN; Carbon fiber; Copolymer; Terpolymer; Solution polymerization; Thermal oxidative stabilization
E-Mail