| 학회 |
한국화학공학회 |
| 학술대회 |
2009년 봄 (04/23 ~ 04/24, 광주 김대중컨벤션센터) |
| 권호 |
15권 1호, p.10 |
| 발표분야 |
고분자 |
| 제목 |
Synthesis and characterization ofcellulose diacetate(CDA)-graft-polycaprolactone(PCL) as a compatibilizer for CDA/PCL blends |
| 초록 |
Cellulose diacetate was grafted with polycaprolactone by ring opening polymerization in the melt state at 140℃ using stannous octoate as a catalyst, where CDA with remaining hydroxyl groups worked as an initiator. By using adequate reaction conditions, the grafting reaction proceeded rapidly and was completed within 10~30 min. The grafting reaction was confirmed by FT-IR spectroscopy. The compatibility of the CDA/ PCL blend was enhanced with CDA-g-PCL, whose amount was 3~5 wt.-% of the blend. The tensile strength and morphology of the CDA/PCL blend were determined by UTM and SEM. It was found that the CDA/PCL blend has finer phase domains and an improved interfacial adhesion. Mechanical properties of the CDA/PCL blend were found to be significantly higher than those of the corresponding uncompatibilized CDA/PCL blend. |
| 저자 |
오석빈, 이시영, 조미숙, 이영관
|
| 소속 |
성균관대 |
| 키워드 |
cellulose diacetate; polycaprolactone; compatibilizer
|
| E-Mail |
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| 원문파일 |
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