| 학회 |
한국화학공학회 |
| 학술대회 |
2015년 봄 (04/22 ~ 04/24, 제주 ICC) |
| 권호 |
21권 1호, p.797 |
| 발표분야 |
재료 |
| 제목 |
Highly Crystalline Graphene Integrated Polyaniline Nanostructured Composites for Protecting Steels from Corrosion in Acidic Environment |
| 초록 |
We report on synthesis, characterization and application of highly crystalline graphene integrated polyaniline (PaniGn) nanostructured composites as corrosion protection coatings. The coated surface showed a decline in corrosion current up to ~3-4 orders of magnitude in 0.1 M HCl. SEM reveals several pits on the surface after the corrosion tests. To explain the observations and understand the fate of the composite coating during corrosion, we present here a molecular model using quantum chemical calculations based on density functional theory. The model presents a plausible mechanism of the protection behavior of the composite coating. |
| 저자 |
Neelima Mahato1, Moo Hwan Cho*2
|
| 소속 |
1영남대, 2School of Chemical Engineering |
| 키워드 |
Polyaniline; Graphene; Nanocomposite; Density Functional Theory; HOMO; LUMO; Frontier molecular orbitals; Corrosion Protection Coatings |
| E-Mail |
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| 원문파일 |
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