| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
고분자 구조 및 물성 |
| 제목 |
Cationic cure of Epoxy Resin Initiated by 1-benzyl-3-methylimidazolium-hexafluoroantimonate as a Latent Initiator |
| 초록 |
The latent thermal cationic initiator 1-benzyl-3-methylimidazolium-hexafluoroantimonate (BMH) was newly synthesized and characterized with FT-IR, 1H NMR spectroscopy. The effect of the novel BMH initiator on cure kinetics and thermal properties of difunctional epoxy [diglycidyl ether of bisphenol A (DGEBA)] cationic system was investigated. From DSC measurements of the DGEBA/BMH system, it was found that this system exhibited excellent thermal latent characteristics at a given temperature and revealed complex cure behavior as indicated by multiple exotherms. The conversion and conversion rate of the DGEBA/BMH system increased with increasing the concentration of initiator, attributed to the high activity of BMH. And the thermal property of DGEBA/BMH system was characterized by thermogravimetric analaysis (TGA). |
| 저자 |
남윤희, 장의성, 최승혁, 최봉구, 이진우, 한학수
|
| 소속 |
연세대 |
| 키워드 |
Epoxy resin; Latent initiator; Cationic initiator; Curing behavior
|
| E-Mail |
|
