화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2015년 가을 (10/21 ~ 10/23, 일산 KINTEX)
권호 21권 2호, p.2272
발표분야 촉매 및 반응공학
제목 A green sonochemical synthesis of PdO@silica heterogeneous catalyst for the decarbonylation of aldehydes
초록 PdO nanoparticles have been grown on the silica nanoparticles (SNP) using a green sonochemical method to produced PdO@SNP nanocatalyst. The large surface area of SNP allowed the fine dispersion of PdO without agglomeration. As prepared PdO@SNP was successfully applied for the decarbonylation of alcohol and various aldehydes in the absence of any co-catalyst at moderate temperature. PdO@SNP gave products with high yields and selectivities without leaching which shows that catalyst is totally heterogeneous and can be applied for several turns.
저자 김정원, 최봉길, 김도현, 석승환, Muhammad Asif Hussain
소속 강원대
키워드 sonochemical; paladinum oxide; silica nano particle; heterogeneous catalyst; decarbonylation; aldehyde
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