화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2015년 가을 (10/21 ~ 10/23, 일산 KINTEX)
권호 21권 2호, p.2337
발표분야 환경
제목 Development of high-performance and acidic tolerance of polyethylenimine and polyvinyl chloride composite fiber sorbent for recovery of Pt(IV) from acidic solution
초록 Platinum group metals (PGMs) such as palladium and platinum have been widely used as catalyst in various industries due to their specific chemical and physical properties. However, after their the usage recovery of PGMs has become a vital issue due to their increased demands and limit availability. In this research, a novel composite fiber sorbent (PEI-PVC) using ionic polyethyleneimine (PEI) and polymer polyvinyl chloride (PVC) was developed for recovery of Pt(IV) from acidic solution. The composition ratio of 2.5:1 for PEI:PVC was showed the best Pt(IV) sorption uptake (350 mg/g). The sorption equilibrium state was rapidly reached as thinner thickness of fiber. In addition, the developed PEI-PVC fiber exhibited excellent acid-tolerance in the 0.1 and 1 M HCl solution. These results suggest that PEI-PVC composite fibers can be manufactured in a facile method, high sorption performance and fast kinetics of composite fiber for precious metals.
저자 윤영상, 윤성일, John Kwame Bediako, 김석, 박상원
소속 전북대
키워드 sorption; polyvinyl chloride; polyethyleneimine; platinum; composite sorbent; recovery
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