화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 가을 (10/26 ~ 10/28, 제주국제컨벤션센터(ICCJEJU))
권호 20권 2호
발표분야 정밀화학_포스터
제목 The effect of fluorine functional groups on carbonization of cellulose fibers
초록 Fluorine functional groups in cellulose fibers were introduced by fluorination for increasing of carbonization yield. The surface functional groups and thermal properties of fluorinated cellulose fibers were analyzed by X-ray photoelectron spectroscopy (XPS) and thermogravimetric analysis (TGA), respectively. Carbonization of fluorinated cellulose fibers was accomplished in N2 gas at 800 ℃ for 1h, and the carbonization yield was measured. The content of fluorine functional groups in fluorinated cellulose fibers was increased according to increasing of fluorination temperature. However in high fluorination temperature (at 180 ℃), the content of fluorine functional groups was decreased by the high heat energy during fluorination. Introduced fluorine functional groups increases the carbonization yield of cellulose fibers by increasing of double bond (C=C bond). The carbonization yield was increased 52.5% compared to pure cellulose fibers by fluorination at 120 ℃.
저자 김민일1, 김도영1, 김민지1, 임지선2, 이영석1
소속 1충남대, 2한국화학(연)
키워드 Cellulose fiber; Fluorination; Carbonization; Carbonization yield; Fluorine functional groups
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