화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 봄 (04/23 ~ 04/25, 제주ICC)
권호 14권 1호, p.563
발표분야 에너지/환경
제목 NaClO2에 의한 NO 산화 경로 규명: 가스상 반응의 영향
초록 The oxidation mechanisms of NO with NaClO2 has been investigated experimentally and theoretically, with focusing on the gas phase reaction, where NO has been injected into the the outlet of flow type packed bed reactor filled with NaClO2 reacting with NO2. Based on experiment and simulation results, we have observed that one NO2 molecule passing through NaClO2 powder generated one OClO molecule subsequently oxidized two NO to NO2 molecules. The reaction of NO with NaClO2 leads to the formation of NO2 and then produced NO2 species further react with NaClO2 to generate OClO which also oxidize NO to NO2 plus ClNO and ClNO2.
저자 변영철1, 이기만2, 고동준2, 신동남2, 김경태2, 고경보1, 조무현1, 남궁원1, 목영선3
소속 1포항공과대, 2포항산업과학(연), 3제주대
키워드 NaClO2; NO oxidation; NO2; OClO; ClNO; ClNO2
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