| 초록 |
Due to high ionic conductivity of Na3V2(PO4)3(NVP), stable 3-D structure and high theoretical capacity, NVP is attracting much attention as cathode material of Na-ion system. However, NVP has poor electronic conductivity and it causes poor rate capability and cycle stability. The aim of this research is to form a composites of NVP/rGO (reduced graphene oxide) to further improve electronic conductivity and structural stability, thereby improving the rate capability and cycle stability. The crunch-shaped NVP/rGO composites were made by sol-gel method and ice templating method. Electrochemical tests show that NVP/rGO composites has much more excellent cycle stability and rate capability than pristine NVP. The results show that NVP/rGO can be considered as a candidate for cathode materials with high capacity and stability in hybrid Na-ion systems. |
